Nucleoside        H-boranophosphonates: a new class of boron-containing nucleotide analogues

Renpei Higashida; Natsuhisa Oka; Toshihide Kawanaka; Takeshi Wada

doi:10.1039/B901045A

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NucleosideH-boranophosphonates: a new class of boron-containing nucleotide analogues†

Renpei Higashida,^a Natsuhisa Oka,^a Toshihide Kawanaka^a and Takeshi Wada*^a

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* Corresponding authors

^a Department of Medical Genome Sciences, Graduate School of Frontier Sciences, The University of Tokyo, Bioscience Building 702, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8562, Japan
E-mail: wada@k.u-tokyo.ac.jp
Fax: +81 4 7136 3612
Tel: +81 4 7136 3612

Abstract

A study on the synthesis of nucleosideH-boranophosphonates, a new class of nucleotide analogues having a P→BH₃ and a P–H group, via condensation of the corresponding nucleosides with H-boranophosphonate derivatives is described.

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Supplementary files

Experimental details and NMR spectra PDF (852K)

Article information

DOI: https://doi.org/10.1039/B901045A
Article type: Communication
Submitted: 16 Jan 2009
Accepted: 06 Feb 2009
First published: 19 Feb 2009

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Chem. Commun., 2009, 2466-2468

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Nucleoside H-boranophosphonates: a new class of boron-containing nucleotide analogues

R. Higashida, N. Oka, T. Kawanaka and T. Wada, Chem. Commun., 2009, 2466 DOI: 10.1039/B901045A

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Chemical Communications