Issue 13, 2009
From the journal:

Chemical Communications

1,2,3-Triphosphole derivatives as reactive intermediates†‡

Markus Stubenhofer,a   Christian Kuntz,a   Gábor Balázs,a   Manfred Zabela  and  Manfred Scheer*a  

* Corresponding authors

a Institute of Inorganic Chemistry, University of Regensburg, Regensburg, Germany
E-mail: manfred.scheer@chemie.uni-regensburg.de
Fax: +49 941 943 4439

Abstract

The complexes [Cp*E{W(CO)5}2] (E = P, As; Cp* = C5Me5) react with 1,2-diphosphinobenzene to give 1,2,3-triphosphole and 2-arsa-1,3-diphosphole derivatives as reactive intermediates that dimerise to polycyclic phosphorous and arsenic containing cage compounds.

Graphical abstract: 1,2,3-Triphosphole derivatives as reactive intermediates

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Article information

DOI
https://doi.org/10.1039/B822732B
Article type
Communication
Submitted
17 Dec 2008
Accepted
20 Jan 2009
First published
05 Feb 2009

Chem. Commun., 2009, 1745-1747

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1,2,3-Triphosphole derivatives as reactive intermediates

M. Stubenhofer, C. Kuntz, G. Balázs, M. Zabel and M. Scheer, Chem. Commun., 2009, 1745 DOI: 10.1039/B822732B

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