Polarization-modulation infrared reflection-absorption spectroscopy affording time-resolved simultaneous detection of surface and liquid phase species at catalytic solid–liquid interfaces

Daniel M. Meier; Atsushi Urakawa; Alfons Baiker

doi:10.1039/B911151D

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Analyst

Issue 9, 2009

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Polarization-modulation infrared reflection-absorption spectroscopy affording time-resolved simultaneous detection of surface and liquid phase species at catalytic solid–liquid interfaces

Daniel M. Meier , Atsushi Urakawa and Alfons Baiker

Analyst, 2009, 134, 1779-1780

DOI: 10.1039/B911151D
Received 08 Jun 2009, Accepted 20 Jul 2009
First published on the web 27 Jul 2009

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Polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS) combined with concentration modulation allows simultaneous monitoring of dynamic evolutions of surface and liquid phase species during reactions at catalytic interfaces as demonstrated for the Pt-catalysed oxidation of CO by O₂ in cyclohexane.

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