Organofluoro-silica xerogels as high-performance optical oxygen sensors

Rosaria Ciriminna; Mario Pagliaro

doi:10.1039/B819417C

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Analyst

Issue 8, 2009

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Organofluoro-silica xerogels as high-performance optical oxygen sensors

Rosaria Ciriminna and Mario Pagliaro

Analyst, 2009, 134, 1531-1535

DOI: 10.1039/B819417C
First published on the web 09 Jun 2009

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Abstract
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Ubiquitous oxygen (O₂) is one of the most important analytes to be assessed in medicine, industry and the environment. Due to a number of advantages, miniaturized optical sol–gel sensors are rapidly replacing older electrochemical sensors. This account provides an overview of fluorinated organically modified silicate (ORMOSIL) xerogels as optical chemical sensors and shows how, together with the dye quenching rate, the subtle structural features of an organofluoro-silica matrix is of fundamental importance in determining the overall sensor performance.

Abstract from Analytical Abstracts 2010

Ubiquitous oxygen (O₂) is one of the most important analytes to be assessed in medicine, industry and the environment. Due to a number of advantages, miniaturized optical sol-gel sensors are rapidly replacing older electrochemical sensors. This account provides an overview of fluorinated organically modified silicate (ORMOSIL) xerogels as optical chemical sensors and shows how, together with the dye quenching rate, the subtle structural features of an organofluoro-silica matrix is of fundamental importance in determining the overall sensor performance. (19 references).

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