Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

Katrina H. Jensen; Matthew S. Sigman

doi:10.1039/B813246A

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Organic & Biomolecular Chemistry

Issue 22, 2008

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Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

Katrina H. Jensen and Matthew S. Sigman

Org. Biomol. Chem., 2008, 6, 4083-4088

DOI: 10.1039/B813246A
Received 31 Jul 2008, Accepted 22 Aug 2008
First published on the web 09 Oct 2008

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Alkene difunctionalization, the addition of two functional groups across a double bond, exemplifies a class of reactions with significant synthetic potential. This emerging area examines recent developments of palladium-catalyzed difunctionalization reactions, with a focus on mechanistic strategies that allow for functionalization of a common palladium alkyl intermediate.

Abstract from Catalysts & Catalysed Reactions 2009

A review, with 26 references, discussing the difunctionalisation of alkenes by palladium catalysed reactions, and focussing on strategies involving the reaction of a common palladium alkyl intermediate.

Abstract from Methods in Organic Synthesis 2009

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Organic & Biomolecular Chemistry

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

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