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Issue 8, 2008
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Synthesis of mono- and 1,3-disubstituted allenes from propargylic amines viapalladium-catalysed hydride-transfer reaction

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Abstract

Mono- and 1,3-disubstituted allenes were synthesized from the corresponding propargylamines viapalladium-catalysed hydride-transfer reaction. In the current transformation, propargylic amines can be handled as allenyl anion equivalents and introduced into various electrophiles to be transformed into allenes under palladium-catalyzed conditions.

Graphical abstract: Synthesis of mono- and 1,3-disubstituted allenes from propargylic amines viapalladium-catalysed hydride-transfer reaction

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Publication details

The article was received on 27 Nov 2007, accepted on 01 Feb 2008 and first published on 06 Mar 2008


Article type: Paper
DOI: 10.1039/B718298H
Citation: Org. Biomol. Chem., 2008,6, 1471-1477
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    Synthesis of mono- and 1,3-disubstituted allenes from propargylic amines viapalladium-catalysed hydride-transfer reaction

    H. Nakamura, M. Ishikura, T. Sugiishi, T. Kamakura and J. Biellmann, Org. Biomol. Chem., 2008, 6, 1471
    DOI: 10.1039/B718298H

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