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Issue 4, 2008
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The Claisen rearrangement approach to fused bicyclic medium-ring oxacycles

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Abstract

The synthesis of five fused-bicyclic medium-ring lactones carrying identical ring-fusion to that in the polyether toxins is described using an enolate hydroxylation, intramolecular hydrosilation, Claisen rearrangement sequence.

Graphical abstract: The Claisen rearrangement approach to fused bicyclic medium-ring oxacycles

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Publication details

The article was received on 05 Oct 2007, accepted on 30 Nov 2007 and first published on 04 Jan 2008


Article type: Paper
DOI: 10.1039/B715354F
Citation: Org. Biomol. Chem., 2008,6, 693-702
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    The Claisen rearrangement approach to fused bicyclic medium-ring oxacycles

    J. W. Burton, E. A. Anderson, P. T. O'Sullivan, I. Collins, J. E. Davies, A. D. Bond, N. Feeder and A. B. Holmes, Org. Biomol. Chem., 2008, 6, 693
    DOI: 10.1039/B715354F

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