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Issue 7, 2008
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Halogen bonding interactions with the [Mo3S7Cl6]2−cluster anion in the mixed valence salt [EDT-TTFI2]4[Mo3S7Cl6]·CH3CN

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Abstract

Electrocrystallization of iodinated TTF molecules in presence of trinuclear [Mo3S7Cl6]2−cluster anions provides the first example of radical salts with halogen bonding interactions at the organic/inorganic interface.

Graphical abstract: Halogen bonding interactions with the [Mo3S7Cl6]2−cluster anion in the mixed valence salt [EDT-TTFI2]4[Mo3S7Cl6]·CH3CN

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Publication details

The article was received on 08 Jan 2008, accepted on 30 May 2008 and first published on 12 Jun 2008


Article type: Letter
DOI: 10.1039/B800298C
Citation: New J. Chem., 2008,32, 1103-1109
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    Halogen bonding interactions with the [Mo3S7Cl6]2−cluster anion in the mixed valence salt [EDT-TTFI2]4[Mo3S7Cl6]·CH3CN

    A. Alberola, M. Fourmigué, C. J. Gómez-García, R. Llusar and S. Triguero, New J. Chem., 2008, 32, 1103
    DOI: 10.1039/B800298C

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