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Issue 5, 2008
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Synthesis and structures of luminescent ladder-like lanthanide coordination polymers of 4-hydroxybenzenesulfonate

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Abstract

Reaction of sodium 4-hydroxybenzenesulfonate dihydrate (NaL·2H2O) with LnCl3·6H2O (3 ∶ 1) in refluxing methanol gives the novel isomorphous 1-D framework compounds {[LnL3(H2O)2]·2H2O} (Ln = Tb, Er and Yb) in 46–60% yields; the structures of the compounds have been determined by X-ray crystallography and their luminescence properties determined.

Graphical abstract: Synthesis and structures of luminescent ladder-like lanthanide coordination polymers of 4-hydroxybenzenesulfonate

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Publication details

The article was received on 03 Dec 2007, accepted on 31 Jan 2008 and first published on 08 Feb 2008


Article type: Letter
DOI: 10.1039/B718590A
Citation: New J. Chem., 2008,32, 790-793
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    Synthesis and structures of luminescent ladder-like lanthanide coordination polymers of 4-hydroxybenzenesulfonate

    X. Yang, J. H. Rivers, W. J. McCarty, M. Wiester and R. A. Jones, New J. Chem., 2008, 32, 790
    DOI: 10.1039/B718590A

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