Group 13 chelates in nerve gas agent and pesticide dealkylation

Amitabha Mitra; David A. Atwood; Jeffrey Struss; Daniel J. Williams; Bradley J. McKinney; William R. Creasy; David J. McGarvey; H. Dupont Durst; Roderick Fry

doi:10.1039/B717041F

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New Journal of Chemistry

Issue 5, 2008

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Group 13 chelates in nerve gas agent and pesticide dealkylation

Amitabha Mitra , David A. Atwood , Jeffrey Struss , Daniel J. Williams , Bradley J. McKinney , William R. Creasy , David J. McGarvey , H. Dupont Durst and Roderick Fry

New J. Chem., 2008, 32, 783-785

DOI: 10.1039/B717041F
Received 05 Nov 2007, Accepted 31 Jan 2008
First published on the web 05 Mar 2008
This article is part of the collection: In honour of Jerry Atwood

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Schiff base boron and aluminium bromides have been used to cleave organophosphate nerve agents and pesticides and their simulants: salben(^tBu)[BBr₂]₂ was very effective in cleaving the VX simulants EMPPT and DEPPT and nerve agent VX; salen(^tBu)AlBr was effective in cleaving the nerve agents VX and Soman and the pesticide Diazinon.

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Articles By

Amitabha Mitra
David A. Atwood
Jeffrey Struss
Daniel J. Williams
Bradley J. McKinney
William R. Creasy
David J. McGarvey
H. Dupont Durst
Roderick Fry

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New Journal of Chemistry

Group 13 chelates in nerve gas agent and pesticide dealkylation

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