Molecular tectonics: ribbon type coordination networks based on porphyrins bearing two pyridine or two pyridine N-oxide units

Emmanuel Deiters; Véronique Bulach; Mir Wais Hosseini

doi:10.1039/B708352A

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New Journal of Chemistry

Issue 1, 2008

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Molecular tectonics: ribbon type coordination networks based on porphyrins bearing two pyridine or two pyridine N-oxide units

Emmanuel Deiters , Véronique Bulach and Mir Wais Hosseini

New J. Chem., 2008, 32, 99-104

DOI: 10.1039/B708352A
Received 01 Jun 2007, Accepted 21 Aug 2007
First published on the web 06 Sep 2007

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Abstract
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Upon combining porphyrin based tectons bearing at the 5,10 meso positions either two pyridine or two pyridine N-oxide groups, with Cd²⁺ or Cu²⁺, four ribbon-type 1-D networks were obtained and structurally characterised in the crystalline phase by X-ray diffraction methods. Although, based on tecton’s structural features, the formation of ribbon-type architectures could be anticipated, their deformation, resulting from the geometry of the connecting metal centres as well as the packing forces in the solid state, could not be predicted.

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New Journal of Chemistry

Molecular tectonics: ribbon type coordination networks based on porphyrins bearing two pyridine or two pyridine N-oxide units

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