Toward autonomously operating molecular machines driven by transition-metal catalyst

Kenichi Tanaka; Kazushi Kinbara

doi:10.1039/B801621F

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Molecular BioSystems

Issue 6, 2008

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Toward autonomously operating molecular machines driven by transition-metal catalyst

Kenichi Tanaka and Kazushi Kinbara

Mol. BioSyst., 2008, 4, 512-514

DOI: 10.1039/B801621F
Received 29 Jan 2008, Accepted 07 Apr 2008
First published on the web 18 Apr 2008

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Compounds
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A Vaska-type complex carrying a ferrocene-appended diphosphine ligand was developed as a prototype of autonomous molecular machines that is able to undergo continuous scissoring motion in the presence of diphenylphosphoryl azide and aldehyde.

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Supplementary Info

Synthesis of (1 S,1″ S)- 2. ¹H and ³¹P NMR spectra of (1 S,1″ S)- 2 and the reaction mixtures.
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Crystal structure data
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Molecular BioSystems

Toward autonomously operating molecular machines driven by transition-metal catalyst

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