Olefin metathesis in water using acoustic emulsification

Łukasz Gułajski; Paweł Śledź; Anna Lupa; Karol Grela

doi:10.1039/B719493E

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Green Chemistry

Issue 3, 2008

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Olefin metathesis in water using acoustic emulsification

Łukasz Gułajski , Paweł Śledź , Anna Lupa and Karol Grela

Green Chem., 2008, 10, 271-274

DOI: 10.1039/B719493E
Received 18 Dec 2007, Accepted 11 Jan 2008
First published on the web 25 Jan 2008

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The performance of two commercially available olefin metathesis catalysts in water has been studied. Ultrasonication of the water-insoluble substrates and catalysts in water allowed the formation of stable emulsions without added surfactants, while the smooth catalytic metathesis took place in the water-insoluble emulsion droplets. Ring-closing (RCM), enyne and cross metathesis (CM) of a variety of substrates proceed with remarkable efficiency in water using acoustic emulsification.

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