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Issue 37, 2008
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Isolation and characterisation of a (−)-sparteine coordinated mixed alkyl/amido sodium magnesiate, a chiral variant of an important utility ate base

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Abstract

When a 1 : 1 nBuNa–n,sBu2Mg mixture is treated with two molar equivalents of TMP(H) (TMP = 2,2,6,6-tetramethylpiperidide) and one molar equivalent of (−)-sparteine in hydrocarbon medium, a new chiral mixed-metal, mixed alkyl-amide [{(−)-sparteine}·Na(μ-Bu)(μ-TMP)Mg(TMP)] can be isolated.

Graphical abstract: Isolation and characterisation of a (−)-sparteine coordinated mixed alkyl/amido sodium magnesiate, a chiral variant of an important utility ate base

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Publication details

The article was received on 15 Jul 2008, accepted on 18 Jul 2008 and first published on 05 Aug 2008


Article type: Communication
DOI: 10.1039/B812085B
Citation: Dalton Trans., 2008,0, 4975-4977
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    Isolation and characterisation of a (−)-sparteine coordinated mixed alkyl/amido sodium magnesiate, a chiral variant of an important utility ate base

    A. R. Kennedy and C. T. O'Hara, Dalton Trans., 2008, 0, 4975
    DOI: 10.1039/B812085B

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