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Issue 34, 2008
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Proton storage in the periphery of zirconium(IV) porphyrinogen

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Abstract

The reaction of zirconium(IV) porphyrinogen with water yields a dinuclear complex in which one μ-oxo ligand bridges two ZrIV centres, and two protons are bound to the alpha carbons of two porphyrinogen pyrroles. The reaction establishes the utility of the porphyrinogen macrocycle as a storage site for protons as well as electrons.

Graphical abstract: Proton storage in the periphery of zirconium(iv) porphyrinogen

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Publication details

The article was received on 03 Jun 2008, accepted on 05 Jun 2008 and first published on 26 Jun 2008


Article type: Communication
DOI: 10.1039/B809366K
Citation: Dalton Trans., 2008,0, 4549-4551
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    Proton storage in the periphery of zirconium(IV) porphyrinogen

    J. Bachmann, T. S. Teets and D. G. Nocera, Dalton Trans., 2008, 0, 4549
    DOI: 10.1039/B809366K

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