Jump to main content
Jump to site search

Issue 24, 2008
Previous Article Next Article

Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni12 complex from the use of pyridine-2-amidoxime

Author affiliations

Abstract

The use of pyridine-2-amidoxime in reaction with NiCl2·6H2O in the presence of NaOMe has led to a cationic NiII12cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral NiII ions, but with intercationic interactions also affecting the magnetic properties.

Graphical abstract: Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni12 complex from the use of pyridine-2-amidoxime

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Feb 2008, accepted on 02 Apr 2008 and first published on 16 Apr 2008


Article type: Communication
DOI: 10.1039/B802927J
Citation: Dalton Trans., 2008,0, 3153-3155
  •   Request permissions

    Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni12 complex from the use of pyridine-2-amidoxime

    C. Papatriantafyllopoulou, L. F. Jones, T. D. Nguyen, N. Matamoros-Salvador, L. Cunha-Silva, F. A. Almeida Paz, J. Rocha, M. Evangelisti, E. K. Brechin and S. P. Perlepes, Dalton Trans., 2008, 0, 3153
    DOI: 10.1039/B802927J

Search articles by author

Spotlight

Advertisements