Issue 9, 2008
From the journal:

Dalton Transactions

Cleavage of P–S bonds and oxygenation by a trinuclear iron carboxylate: Synthesis and structures of iron clusters containing group 15/16 anions†‡§

Tatiana V. Mitkina,a   Yanhua Lan,a   Valeriu Mereacre,a   Weifeng Shi,a   Annie K. Powella  and  Alexander Rothenberger*ab  

* Corresponding authors

a Institut für Anorganische Chemie der Universität Karlsruhe, Geb. 30.45, Engesserstr. 15a, Karlsruhe, Germany

b Institut für Nanotechnologie, Forschungszentrum Karlsruhe GmbH, Postfach 3640, Karlsruhe, Germany
E-mail: ar252@chemie.uni-karlsruhe.de

Abstract

The first reactions of the trinuclear oxygen-centred iron carboxylate [Fe3(µ3-O)(µ2-piv)6(H2O)3](piv) (piv = tBuCOO−) with the neutral ligand precursor [RP(S)(µ-S)]2 (R = 4-anisyl) are reported.

Graphical abstract: Cleavage of P–S bonds and oxygenation by a trinuclear iron carboxylate: Synthesis and structures of iron clusters containing group 15/16 anions

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Article information

DOI
https://doi.org/10.1039/B717583C
Article type
Communication
Submitted
13 Nov 2007
Accepted
02 Jan 2008
First published
23 Jan 2008

Dalton Trans., 2008, 1136-1139

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Cleavage of P–S bonds and oxygenation by a trinuclear iron carboxylate: Synthesis and structures of iron clusters containing group 15/16 anions

T. V. Mitkina, Y. Lan, V. Mereacre, W. Shi, A. K. Powell and A. Rothenberger, Dalton Trans., 2008, 1136 DOI: 10.1039/B717583C

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