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Issue 5, 2008
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Contrasting bonding modes of a tridentate bis(oxazoline)phosphine ligand in cobalt and ironvs.palladium complexes: unprecedented N,N-coordination for a N,P,N ligand

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Abstract

Unexpected N,N-coordination of the potentially tridentate N,P,N-ligand bis(2-oxazolin-2,5,5-trimethyl)phenylphosphine occurs in Co(II) and Fe(II) complexes, in contrast to the P,N- or N,P,N-coordination modes observed in Pd(II) complexes; this leads to the formation of unprecedented eight-membered ring chelates.

Graphical abstract: Contrasting bonding modes of a tridentate bis(oxazoline)phosphine ligand in cobalt and ironvs.palladium complexes: unprecedented N,N-coordination for a N,P,N ligand

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Publication details

The article was received on 31 Aug 2007, accepted on 05 Nov 2007 and first published on 16 Nov 2007


Article type: Communication
DOI: 10.1039/B717021C
Citation: Dalton Trans., 2008,0, 585-587
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    Contrasting bonding modes of a tridentate bis(oxazoline)phosphine ligand in cobalt and ironvs.palladium complexes: unprecedented N,N-coordination for a N,P,N ligand

    A. Kermagoret and P. Braunstein, Dalton Trans., 2008, 0, 585
    DOI: 10.1039/B717021C

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