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Issue 11, 2008
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Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control

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Abstract

Three discrete cobalt-substituted silicotungstates, [Co3(H2O)(B-β-SiW9O34)(B-β-SiW8O29(OH)2)]12− (1), [Co3(H2O)(B-α-SiW9O34)(B-β-SiW8O31)]14− (2), and [Co9Cl2(OH)3(H2O)9(B-β-SiW8O31)3]17− (3), have been synthesized using a synthetic approach involving Co(II) ions, the dilacunary [γ-SiW10O36]8−polyanion and a bulky organic cation in basic media; all three compounds have been fully characterized and their position as structural intermediates in Co-containing silicotungstate chemistry is described.

Graphical abstract: Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control

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Publication details

The article was received on 18 Oct 2007, accepted on 14 Jan 2008 and first published on 06 Feb 2008


Article type: Communication
DOI: 10.1039/B715885H
Citation: Dalton Trans., 2008, 1415-1417
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    Isolation of extendable transition metal incorporated polyoxometalate intermediates with structural control

    S. G. Mitchell, C. Ritchie, D. Long and L. Cronin, Dalton Trans., 2008, 1415
    DOI: 10.1039/B715885H

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