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Issue 12, 2008
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Versatile tools in the construction of substituted 2,2′-bipyridines—cross-coupling reactions with tin, zinc and boron compounds

Marko Hapke,*a  Lars Brandtb  and  Arne Lützen*c 
Author affiliations

* Corresponding authors

a Leibniz-Institut für Katalyse e. V. an der Universität Rostock (LIKAT), Albert-Einstein-Str. 29a, Rostock, Germany
E-mail: marko.hapke@catalysis.de
Web: http://www.catalysis.de

b Carl von Ossietzky-University of Oldenburg, Institute for Pure and Applied Chemistry, Technical Chemistry, P.O. Box 2503, Oldenburg, Germany

c Kekulé-Institute of Organic Chemistry and Biochemistry, University of Bonn, Gerhard-Domagk-Str. 1, Bonn, Germany
E-mail: arne.luetzen@uni-bonn.de
Fax: +49 228 739608
Tel: 49 228 737533

Abstract

2,2′-Bipyridines are among the most widely used classes of chelating ligands that have found applications in the fields of coordination chemistry, supra-, nano- and macromolecular chemistry, analytical and photochemistry, but also in asymmetric synthesis and natural product chemistry. Hence, there is a huge demand for efficient synthetic approaches to functionalized derivatives. Modern cross-coupling procedures have been proven to be particularly effective in this context. This critical review will give an overview about the advances made so far focussing mainly on cross-coupling reactions with tin, zinc and boron compounds for the achievement of interesting, versatile and unusual substitution patterns (156 references).

Graphical abstract: Versatile tools in the construction of substituted 2,2′-bipyridines—cross-coupling reactions with tin, zinc and boron compounds

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Publication details

The article was received on 19 Aug 2008 and first published on 24 Oct 2008


Article type: Critical Review
DOI: 10.1039/B810973G
Citation: Chem. Soc. Rev., 2008,37, 2782-2797
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    Versatile tools in the construction of substituted 2,2′-bipyridines—cross-coupling reactions with tin, zinc and boron compounds

    M. Hapke, L. Brandt and A. Lützen, Chem. Soc. Rev., 2008, 37, 2782
    DOI: 10.1039/B810973G

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