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Issue 25, 2008
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Shape-dependent electrocatalysis: methanol and formic acid electrooxidation on preferentially oriented Pt nanoparticles

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Abstract

Reactivity towards methanol and formic acid electrooxidation on Pt nanoparticles with well characterised surfaces were studied and compared with the behaviour of single crystal electrodes with basal orientations. Polyoriented and preferential (100), (111) and (100)–(111) Pt nanoparticles were synthesised, cleaned preserving its surface structure, characterised and employed to evaluate the influence of the surface structure/shape of the Pt nanoparticles on these two relevant electrochemical reactions. The results pointed out that, in agreement with fundamental studies with Pt single crystal electrodes, the surface structure of the electrodes plays an important role on the reactivity of both oxidation processes, and thus the electrocatalytic properties strongly depend on the surface structure/shape of the nanoparticles, in particular on the presence of sites with (111) symmetry. These findings open the possibility of designing new and better electrocatalytic materials using decorated shape-controlled Pt nanoparticles as previously described with Pt single crystal electrodes.

Graphical abstract: Shape-dependent electrocatalysis: methanol and formic acid electrooxidation on preferentially oriented Pt nanoparticles

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Publication details

The article was received on 18 Feb 2008, accepted on 09 Apr 2008 and first published on 14 May 2008


Article type: Paper
DOI: 10.1039/B802703J
Citation: Phys. Chem. Chem. Phys., 2008,10, 3689-3698
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    Shape-dependent electrocatalysis: methanol and formic acid electrooxidation on preferentially oriented Pt nanoparticles

    J. Solla-Gullón, F. J. Vidal-Iglesias, A. López-Cudero, E. Garnier, J. M. Feliu and A. Aldaz, Phys. Chem. Chem. Phys., 2008, 10, 3689
    DOI: 10.1039/B802703J

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