1,3,5-Trinitrobenzene, 2,4,6-trinitrotoluene and 1-methoxy-2,4,6-trinitrobenzene undergoes reversible dimerization, after electrochemical reduction of two units of corresponding anion radical. The π-dimer formed captures molecular oxygen (O2) leading to a σHo-o-adduct, in an atmosphere of oxygen or even air. The σHo-o-adduct is able to reversibly bind and remove dioxygen after an external redox stimulus.
The article was received on 25 Jan 2008, accepted on 16 Apr 2008 and first published on 13 Jun 2008
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