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Issue 2, 2008
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Response to Comment on Autoionization at the surface of neat water: is the top layer pH neutral, basic, or acidic? by J. K. Beattie, Phys. Chem. Chem. Phys., 2007, 9, DOI: 10.1039/b713702h

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Abstract

In this Response we define the sublayers of the water/vapor interface for clarity. We point out that the experimental evidence for surface enhancement of hydronium but not hydroxide is consistent across a broad concentration range and discuss the limitations of the molecular dynamics simulation at pH = 7 while noting that the computational results are only weakly dependent on concentration.

Graphical abstract: Response to Comment on Autoionization at the surface of neat water: is the top layer pH neutral, basic, or acidic? by J. K. Beattie, Phys. Chem. Chem. Phys., 2007, 9, DOI: 10.1039/b713702h

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Publication details

The article was received on 24 Sep 2007, accepted on 19 Oct 2007 and first published on 01 Nov 2007


Article type: Comment
DOI: 10.1039/B714723F
Citation: Phys. Chem. Chem. Phys., 2008,10, 332-333
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    Response to Comment on Autoionization at the surface of neat water: is the top layer pH neutral, basic, or acidic? by J. K. Beattie, Phys. Chem. Chem. Phys., 2007, 9, DOI: 10.1039/b713702h

    R. Vácha, V. Buch, A. Milet, J. P. Devlin and P. Jungwirth, Phys. Chem. Chem. Phys., 2008, 10, 332
    DOI: 10.1039/B714723F

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