Issue 10, 2008
From the journal:

CrystEngComm

Contrasting crystallographic signatures of Ag(i)- and Cu(ii)-N6,N6′- bisadenine complexes: extended vs. foldback geometries†

Ashutosh Kumar Mishra,a   Chandra Shekhar Purohita  and  Sandeep Verma*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology—Kanpur, Kanpur, UP, India
E-mail: sverma@iitk.ac.in

Abstract

We report crystallographic studies with N6,N6′-crosslinked bisadenine derivative, where complexation with Ag(I) exhibits a pentacoordination mode affording a molecular box, while interaction with Cu(II) results in an intramolecular complex.

Graphical abstract: Contrasting crystallographic signatures of Ag(i)- and Cu(ii)-N6,N6′- bisadenine complexes: extended vs. foldback geometries

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Article information

DOI
https://doi.org/10.1039/B811205N
Article type
Communication
Submitted
01 Jul 2008
Accepted
08 Jul 2008
First published
31 Jul 2008

CrystEngComm, 2008,10, 1296-1298

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Contrasting crystallographic signatures of Ag(I)- and Cu(II)-N6,N6′- bisadenine complexes: extended vs. foldback geometries

A. K. Mishra, C. S. Purohit and S. Verma, CrystEngComm, 2008, 10, 1296 DOI: 10.1039/B811205N

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