Halogen bonded supramolecular complexes and networks

Kari Rissanen

doi:10.1039/B803329N

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CrystEngComm

Issue 9, 2008

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Halogen bonded supramolecular complexes and networks

Kari Rissanen

CrystEngComm, 2008, 10, 1107-1113

DOI: 10.1039/B803329N
Received 26 Feb 2008, Accepted 26 Mar 2008
First published on the web 09 May 2008

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Abstract
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In spite of some controversy of the true nature of the interaction between polarized halogen atoms and neutral or charged Lewis bases, termed “halogen bonding”, as a primary interaction, it is a very useful new tool/way to construct supramolecular complexes and networks. This is especially true in solid state supramolecular chemistry where utilization of weak intermolecular interactions such as halogen bonding opens up new insights to materials design and supramolecular synthesis.

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Halogen bonded supramolecular complexes and networks

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