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Issue 7, 2008
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A mixed-linker porphyrin framework with CdI2-type topology

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Abstract

A novel metal–organic framework, [(Co(cis-ZnDCPP)(bpy)]·4DMF·H2O (cis-ZnDCPP = zinc 5,10-di(4-carboxyphenyl)-15,20-diphenylporphyrin; bpy = 4,4′-bipyridine; DMF = dimethyl formamide), has been synthesized from the solvothermal reaction and exhibits unique CdI2 layers constructed from paddle-wheel buiding units, Co2(COO)4, cis-ZnDCPP, and 4,4′-bipyridine linker.

Graphical abstract: A mixed-linker porphyrin framework with CdI2-type topology

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Publication details

The article was received on 02 Jan 2008, accepted on 18 Mar 2008 and first published on 09 Apr 2008


Article type: Communication
DOI: 10.1039/B720035H
Citation: CrystEngComm, 2008,10, 824-826
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    A mixed-linker porphyrin framework with CdI2-type topology

    E. Choi, P. M. Barron, R. W. Novotney, C. Hu, Y. Kwon and W. Choe, CrystEngComm, 2008, 10, 824
    DOI: 10.1039/B720035H

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