Issue 47, 2008
From the journal:

Chemical Communications

Catalytic aziridination of electron-deficient olefins with an N-chloro-N-sodio carbamate and application of this novel method to asymmetric synthesis†

Satoshi Minakata,*a   Yuta Murakami,a   Ryoji Tsuruoka,a   Shinsuke Kitanakaa  and  Mitsuo Komatsua  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Japan
E-mail: minakata@chem.eng.osaka-u.ac.jp
Fax: +81 6-6879-7402

Abstract

A new method for the aziridination of electron-deficient olefins using an N-chloro-N-sodio carbamate is described; the reaction was promoted by phase-transfer catalysis (solid–liquid) and afforded aziridines from α,β-unsaturated ketones, esters, sulfones and amides.

Graphical abstract: Catalytic aziridination of electron-deficient olefins with an N-chloro-N-sodio carbamate and application of this novel method to asymmetric synthesis

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Article information

DOI
https://doi.org/10.1039/B812978A
Article type
Communication
Submitted
29 Jul 2008
Accepted
09 Sep 2008
First published
29 Oct 2008

Chem. Commun., 2008, 6363-6365

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Catalytic aziridination of electron-deficient olefins with an N-chloro-N-sodio carbamate and application of this novel method to asymmetric synthesis

S. Minakata, Y. Murakami, R. Tsuruoka, S. Kitanaka and M. Komatsu, Chem. Commun., 2008, 6363 DOI: 10.1039/B812978A

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