Molecular tectonics: control of pore size and polarity in 3-D hexagonal coordination networks based on porphyrins and a zinc cation

Elisabeth Kühn; Véronique Bulach; Mir Wais Hosseini

doi:10.1039/B812831F

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Chemical Communications

Issue 41, 2008

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Molecular tectonics: control of pore size and polarity in 3-D hexagonal coordination networks based on porphyrins and a zinc cation

Elisabeth Kühn , Véronique Bulach and Mir Wais Hosseini

Chem. Commun., 2008, 5104-5106

DOI: 10.1039/B812831F
Received 25 Jul 2008, Accepted 09 Sep 2008
First published on the web 24 Sep 2008

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Abstract
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In the crystalline phase, porphyrin derivatives based on two 4-pyridyl units at the 5 and 15 meso positions and two 4-aryl moieties bearing various groups (CN, OMe, OH and CF₃) at the 10 and 20 meso positions lead, in the presence of a zinc dication, to the formation of robust 3-D networks presenting hexagonal channels: both the size and the polarity of the pores were tuned by the nature of the substituents attached to the two aryl groups.

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Chemical Communications

Molecular tectonics: control of pore size and polarity in 3-D hexagonal coordination networks based on porphyrins and a zinc cation

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