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Issue 44, 2008
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Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide: preparation of scCO2 soluble polymers with low catalytic residues

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Abstract

Synthesis of poly(2,2,2-trifluoroethyl methacrylate) by supported ATRP was investigated in supercritical carbon dioxide using a copper salt ligated to a polymeric ligand immobilised onto silica; after polymerisation, fluorinated polymers with well defined molecular weight and low polydispersity were obtained.

Graphical abstract: Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide: preparation of scCO2 soluble polymers with low catalytic residues

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Publication details

The article was received on 17 Jul 2008, accepted on 19 Aug 2008 and first published on 01 Oct 2008


Article type: Communication
DOI: 10.1039/B812297K
Citation: Chem. Commun., 2008,0, 5803-5805
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    Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide: preparation of scCO2 soluble polymers with low catalytic residues

    B. Grignard, C. Calberg, C. Jérôme, W. Wang, S. Howdle and C. Detrembleur, Chem. Commun., 2008, 0, 5803
    DOI: 10.1039/B812297K

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