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Issue 43, 2008
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A two-step spin crossover mononuclear iron(II) complex with a [HS–LS–LS] intermediate phase

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Abstract

The two-step spin crossover of a new mononuclear iron(II) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS–LSLS] motif.

Graphical abstract: A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase

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Publication details

The article was received on 09 Jul 2008, accepted on 08 Aug 2008 and first published on 29 Sep 2008


Article type: Communication
DOI: 10.1039/B811746B
Citation: Chem. Commun., 2008,0, 5619-5621
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    A two-step spin crossover mononuclear iron(II) complex with a [HS–LS–LS] intermediate phase

    S. Bonnet, M. A. Siegler, J. S. Costa, G. Molnár, A. Bousseksou, A. L. Spek, P. Gamez and J. Reedijk, Chem. Commun., 2008, 0, 5619
    DOI: 10.1039/B811746B

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