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Issue 46, 2008
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Synthesis of a new olefin polymerization catalyst supported by an sp3-C donor via insertion of a ligand-appended alkene into the Hf–C bond of a neutral pyridylamidohafnium trimethyl complex

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Abstract

A new living and isoselective propylene polymerization precatalyst was generated via the intramolecular insertion of a ligand-appended vinyl group into the Hf–C bond of a neutral pyridylamidohafnium trimethyl complex.

Graphical abstract: Synthesis of a new olefin polymerization catalyst supported by an sp3-C donor via insertion of a ligand-appended alkene into the Hf–C bond of a neutral pyridylamidohafnium trimethyl complex

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Publication details

The article was received on 04 Jul 2008, accepted on 17 Sep 2008 and first published on 22 Oct 2008


Article type: Communication
DOI: 10.1039/B811384J
Citation: Chem. Commun., 2008,0, 6137-6139
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    Synthesis of a new olefin polymerization catalyst supported by an sp3-C donor via insertion of a ligand-appended alkene into the Hf–C bond of a neutral pyridylamidohafnium trimethyl complex

    G. J. Domski, J. B. Edson, I. Keresztes, E. B. Lobkovsky and G. W. Coates, Chem. Commun., 2008, 0, 6137
    DOI: 10.1039/B811384J

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