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Issue 44, 2008
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A proton–hydride diiron complex with a base-containing diphosphine ligand relevant to the [FeFe]-hydrogenase active site

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Abstract

A diiron dithiolate complex holding a μ-hydride on the iron atoms and a proton on the basic site of a chelating diphosphine ligand was prepared and crystallographically characterized as a structural model of the [FeFe]-hydrogenase active site, and its molecular structure shows the Hμ⋯HN+ distance is 3.934 Å.

Graphical abstract: A proton–hydride diiron complex with a base-containing diphosphine ligand relevant to the [FeFe]-hydrogenase active site

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Publication details

The article was received on 03 Jul 2008, accepted on 20 Aug 2008 and first published on 01 Oct 2008


Article type: Communication
DOI: 10.1039/B811352A
Citation: Chem. Commun., 2008,0, 5800-5802
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    A proton–hydride diiron complex with a base-containing diphosphine ligand relevant to the [FeFe]-hydrogenase active site

    N. Wang, M. Wang, T. Zhang, P. Li, J. Liu and L. Sun, Chem. Commun., 2008, 0, 5800
    DOI: 10.1039/B811352A

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