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Issue 39, 2008
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Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O529-SO3)]7−

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Abstract

A polyoxomolybdenum/vanadium-sulfite {M18} cluster-based compound, [MoVI11VV5VIV2O529-SO3)]7−, is reported that exhibits a unique structural motif, arising from the incorporation of five VV and two VIV ions into a {M18} cluster framework templated by SO32−; this cluster compostion was first identified using cryospray mass spectrometry.

Graphical abstract: Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O52(μ9-SO3)]7−

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Publication details

The article was received on 02 Jul 2008, accepted on 05 Aug 2008 and first published on 15 Sep 2008


Article type: Communication
DOI: 10.1039/B811279G
Citation: Chem. Commun., 2008, 4703-4705
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    Solution identification and solid state characterisation of a heterometallic polyoxometalate {Mo11V7}: [MoVI11VV5VIV2O529-SO3)]7−

    H. N. Miras, D. J. Stone, E. J. L. McInnes, R. G. Raptis, P. Baran, G. I. Chilas, M. P. Sigalas, T. A. Kabanos and L. Cronin, Chem. Commun., 2008, 4703
    DOI: 10.1039/B811279G

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