Gas-phase synthesis of the rare-gas carbene cation ArCH2+ using doubly ionised bromomethane as a superelectrophilic reagent

Daniela Ascenzi; Paolo Tosi; Jana Roithová; Detlef Schröder

doi:10.1039/B811115D

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Chemical Communications

Issue 34, 2008

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Gas-phase synthesis of the rare-gas carbene cation ArCH₂⁺ using doubly ionised bromomethane as a superelectrophilic reagent

Daniela Ascenzi , Paolo Tosi , Jana Roithová and Detlef Schröder

Chem. Commun., 2008, 4055-4057

DOI: 10.1039/B811115D
Received 30 Jun 2008, Accepted 11 Jul 2008
First published on the web 29 Jul 2008

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The bimolecular reaction of mass-selected CH₃Br²⁺/CH₂BrH²⁺ dications with argon leads to the rare-gas carbene cation ArCH₂⁺, which represents an example of a new kind of organo rare-gas compound.

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Chemical Communications

Gas-phase synthesis of the rare-gas carbene cation ArCH₂⁺ using doubly ionised bromomethane as a superelectrophilic reagent

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