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Issue 34, 2008
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Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis

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Abstract

The Pd-catalysed asymmetric intramolecular α-arylation of amideenolates containing heteroatom substituents gives chiral 3-alkoxy or 3-aminooxindoles in high yield and with enantioselectivities up to 97% ee when a new chiral N-heterocyclic carbene ligand is used.

Graphical abstract: Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis

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Supplementary files

Publication details

The article was received on 26 Jun 2008, accepted on 18 Jul 2008 and first published on 01 Aug 2008


Article type: Communication
DOI: 10.1039/B810858G
Citation: Chem. Commun., 2008,0, 4040-4042
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    Chiral N-heterocyclic carbene ligands for asymmetric catalytic oxindole synthesis

    Y. Jia, J. M. Hillgren, E. L. Watson, S. P. Marsden and E. P. Kündig, Chem. Commun., 2008, 0, 4040
    DOI: 10.1039/B810858G

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