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Issue 41, 2008
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Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction

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Abstract

The microporous metal–organic framework Ni2(dhtp) (H4dhtp = 2,5-dihydroxyterephthalic acid) shows distinct end-on CO2 coordination to coordinatively unsaturated nickel sites giving rise to high CO2 adsorption capacity at sub-atmospheric pressures and ambient temperatures.

Graphical abstract: Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction

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Publication details

The article was received on 23 Jun 2008, accepted on 09 Sep 2008 and first published on 24 Sep 2008


Article type: Communication
DOI: 10.1039/B810574J
Citation: Chem. Commun., 2008,0, 5125-5127
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    Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction

    P. D. C. Dietzel, R. E. Johnsen, H. Fjellvåg, S. Bordiga, E. Groppo, S. Chavan and R. Blom, Chem. Commun., 2008, 0, 5125
    DOI: 10.1039/B810574J

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