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Issue 40, 2008
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Designed molecular propellers based on tetraarylterephthalamide and their chiroptical properties induced by biased helicity through transmission of point chirality

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Abstract

The syn-atropisomers of the title bis(tertiary amide)s were designed as six-bladed molecular propellers based on the “directing effects” of amide dipoles; the helicity of the propeller is biased to prefer one handedness upon the attachment of point chirality to the amide nitrogens to attain stronger circular-dichroism activity than for the non-propeller-shaped anti-isomers.

Graphical abstract: Designed molecular propellers based on tetraarylterephthalamide and their chiroptical properties induced by biased helicity through transmission of point chirality

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Publication details

The article was received on 02 Jun 2008, accepted on 23 Jul 2008 and first published on 10 Sep 2008


Article type: Communication
DOI: 10.1039/B808936A
Citation: Chem. Commun., 2008,0, 4906-4908
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    Designed molecular propellers based on tetraarylterephthalamide and their chiroptical properties induced by biased helicity through transmission of point chirality

    R. Katoono, H. Kawai, K. Fujiwara and T. Suzuki, Chem. Commun., 2008, 0, 4906
    DOI: 10.1039/B808936A

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