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Issue 42, 2008
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Orthogonal or simultaneous use of disulfide and hydrazone exchange in dynamic covalent chemistry in aqueous solution

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Abstract

Hydrazone and disulfide exchange have been combined in a single system, but can be addressed independently: by adjusting the pH of the solution from acidic to mildly basic it is possible to switch from exclusively hydrazone exchange to exclusively disulfide exchange, while at intermediate pH both reactions occur simultaneously.

Graphical abstract: Orthogonal or simultaneous use of disulfide and hydrazone exchange in dynamic covalent chemistry in aqueous solution

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Publication details

The article was received on 22 May 2008, accepted on 16 Jul 2008 and first published on 11 Sep 2008


Article type: Communication
DOI: 10.1039/B808725C
Citation: Chem. Commun., 2008,0, 5301-5303
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    Orthogonal or simultaneous use of disulfide and hydrazone exchange in dynamic covalent chemistry in aqueous solution

    Z. Rodriguez-Docampo and S. Otto, Chem. Commun., 2008, 0, 5301
    DOI: 10.1039/B808725C

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