Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

Luciano Cuesta; Elisa Tomat; Vincent M. Lynch; Jonathan L. Sessler

doi:10.1039/B807126H

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Chemical Communications

Issue 32, 2008

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Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

Luciano Cuesta , Elisa Tomat , Vincent M. Lynch and Jonathan L. Sessler

Chem. Commun., 2008, 3744-3746

DOI: 10.1039/B807126H
Received 01 May 2008, Accepted 11 Jun 2008
First published on the web 01 Jul 2008

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The synthesis of binuclear organometallic ruthenium complexes of an expanded porphyrin-type macrocycle is reported; pyrrolic hydrogen bonding donors were found to interact with ancillary ligands in the primary coordination sphere and to stabilize coordinated dioxygen in an η²-fashion.

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Chemical Communications

Binuclear organometallic ruthenium complexes of a Schiff base expanded porphyrin

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