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Issue 28, 2008
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Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

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Abstract

This communication details the Pd-catalyzed decarboxylation of selenocarbonates; use of a chiral nonracemic catalyst affords enantioenriched allyl selenides which undergo stereospecific [2,3]-sigmatropic rearrangements to form enantioenriched allylic amines and chlorides.

Graphical abstract: Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

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Publication details

The article was received on 25 Apr 2008, accepted on 02 May 2008 and first published on 10 Jun 2008


Article type: Communication
DOI: 10.1039/B806949B
Citation: Chem. Commun., 2008,0, 3311-3313
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    Synthesis of allyl selenides by palladium-catalyzed decarboxylative coupling

    S. R. Waetzig and J. A. Tunge, Chem. Commun., 2008, 0, 3311
    DOI: 10.1039/B806949B

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