Jump to main content
Jump to site search

Issue 37, 2008
Previous Article Next Article

BiPh3—A convenient synthon for heavy alkaline-earth metal amides

Author affiliations

Abstract

Environmentally friendly, commercially available BiPh3 reacts with heavy alkaline-earth metals (Ae) and bulky trimethylsilylamines to give the corresponding amides [Ae{N(SiMe3)(R)}2(thf)n] (R = SiMe3, 2,4,6-Me3C6H2, 2,6-iPr2C6H3) in good yields, providing proof of concept for a general synthetic method.

Graphical abstract: BiPh3—A convenient synthon for heavy alkaline-earth metal amides

Back to tab navigation

Supplementary files

Publication details

The article was received on 24 Apr 2008, accepted on 16 Jun 2008 and first published on 31 Jul 2008


Article type: Communication
DOI: 10.1039/B806948D
Citation: Chem. Commun., 2008,0, 4490-4492
  •   Request permissions

    BiPh3—A convenient synthon for heavy alkaline-earth metal amides

    M. M. Gillett-Kunnath, J. G. MacLellan, C. M. Forsyth, P. C. Andrews, G. B. Deacon and K. Ruhlandt-Senge, Chem. Commun., 2008, 0, 4490
    DOI: 10.1039/B806948D

Search articles by author

Spotlight

Advertisements