Synthesis and reactivity of bis-pentamethylcyclopentadienyl diiododialane (Cp*AlI)2: an aluminium(II) precursor to (Cp*Al)4

Stefan G. Minasian; John Arnold

doi:10.1039/B806804F

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Chemical Communications

Issue 34, 2008

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Synthesis and reactivity of bis-pentamethylcyclopentadienyl diiododialane (CpAlI)₂: an aluminium(II) precursor to (CpAl)₄

Stefan G. Minasian and John Arnold

Chem. Commun., 2008, 4043-4045

DOI: 10.1039/B806804F
Received 22 Apr 2008, Accepted 30 Jun 2008
First published on the web 24 Jul 2008

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Use of an alternative aluminium(III) starting material has led to the isolation of a new aluminium(II) diiododialane, which functions as an intermediate in the synthesis of (Cp*Al)₄, reacts oxidatively with methyllithium, and undergoes oxidative cleavage of the Al–Al bond with an aryl azide.

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Chemical Communications

Synthesis and reactivity of bis-pentamethylcyclopentadienyl diiododialane (CpAlI)₂: an aluminium(II) precursor to (CpAl)₄

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