Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes

Liam P. Spencer; Robyn L. Gdula; Trevor W. Hayton; Brian L. Scott; James M. Boncella

doi:10.1039/B806075D

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Chemical Communications

Issue 40, 2008

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Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes

Liam P. Spencer , Robyn L. Gdula , Trevor W. Hayton , Brian L. Scott and James M. Boncella

Chem. Commun., 2008, 4986-4988

DOI: 10.1039/B806075D
Received 11 Apr 2008, Accepted 19 Jul 2008
First published on the web 09 Sep 2008

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Abstract
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The bis(imido) uranium(VI)–C₅H₅ and –C₅Me₅ complexes (C₅H₅)₂U(N^tBu)₂, (C₅Me₅)₂U(N^tBu)₂, (C₅H₅)U(N^tBu)₂(I)(dmpe), and (C₅H₅)₂U(N^tBu)₂(dmpe) can be synthesized from reactions between U(N^tBu)₂(I)₂(L)_x (L = THF, x = 2; L = dmpe, x = 1) and Na(C₅R₅) (R = H, Me); these complexes represent the first structurally characterized C₅H₅-compounds of uranium(VI) and they further highlight the differences between UO₂²⁺ and the bis(imido) fragment.

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Liam P. Spencer
Robyn L. Gdula
Trevor W. Hayton
Brian L. Scott
James M. Boncella

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Chemical Communications

Synthesis and reactivity of bis(imido) uranium(VI) cyclopentadienyl complexes

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