Reactivity of a Co(I) [N2P2] complex with azides: evidence for a transient Co(III) imido species

Wayne A. Chomitz; John Arnold

doi:10.1039/B804754E

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Chemical Communications

Issue 31, 2008

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Reactivity of a Co(I) [N₂P₂] complex with azides: evidence for a transient Co(III) imido species

Wayne A. Chomitz and John Arnold

Chem. Commun., 2008, 3648-3650

DOI: 10.1039/B804754E
Received 19 Mar 2008, Accepted 21 May 2008
First published on the web 23 Jun 2008

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The synthesis of a monomeric Co(I) complex supported by a multidentate monoanionic [N₂P₂] ligand is described; interaction with aryl azides at low temperature generates a species whose reactivity is consistent with imido (“Co [double bond, length as m-dash] NR”) character.

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Chemical Communications

Reactivity of a Co(I) [N₂P₂] complex with azides: evidence for a transient Co(III) imido species

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