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Issue 27, 2008
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Room-temperature activation of aryl chlorides in Suzuki–Miyaura coupling using a [Pd(μ-Cl)Cl(NHC)]2 complex (NHC = N-heterocyclic carbene)

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Abstract

A straightforwardly synthesised complex, [Pd(μ-Cl)Cl(NHC)]2 (NHC = bis(2,6-diisopropylphenyl)imidazol-2-ylidene, IPr), has been employed to mediate Suzuki–Miyaura reactions involving aryl chlorides at very low catalyst loadings and at room temperature.

Graphical abstract: Room-temperature activation of aryl chlorides in Suzuki–Miyaura coupling using a [Pd(μ-Cl)Cl(NHC)]2 complex (NHC = N-heterocyclic carbene)

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Publication details

The article was received on 19 Mar 2008, accepted on 11 Apr 2008 and first published on 12 May 2008


Article type: Communication
DOI: 10.1039/B804695F
Citation: Chem. Commun., 2008,0, 3190-3192
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    Room-temperature activation of aryl chlorides in Suzuki–Miyaura coupling using a [Pd(μ-Cl)Cl(NHC)]2 complex (NHC = N-heterocyclic carbene)

    O. Diebolt, P. Braunstein, S. P. Nolan and C. S. J. Cazin, Chem. Commun., 2008, 0, 3190
    DOI: 10.1039/B804695F

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