Jump to main content
Jump to site search

Issue 31, 2008
Previous Article Next Article

Fluorous synthesis of allylic fluorides: C–F bond formation as the detagging process

Author affiliations

Abstract

A novel fluorous tagging–detagging strategy has been developed featuring a fluorination as the detagging process; fluorous allylsilanes were prepared by cross-metathesis and subsequently subjected to electrophilic fluorodesilylation; Selectfluor was used as the detagging reagent; the resulting allylic fluorides were successfully purified by fluorous solid phase extraction.

Graphical abstract: Fluorous synthesis of allylic fluorides: C–F bond formation as the detagging process

Back to tab navigation

Supplementary files

Publication details

The article was received on 17 Mar 2008, accepted on 02 May 2008 and first published on 04 Jun 2008


Article type: Communication
DOI: 10.1039/B804484H
Citation: Chem. Commun., 2008, 3622-3624
  •   Request permissions

    Fluorous synthesis of allylic fluorides: C–F bond formation as the detagging process

    S. Boldon, J. E. Moore and V. Gouverneur, Chem. Commun., 2008, 3622
    DOI: 10.1039/B804484H

Search articles by author

Spotlight

Advertisements