Can the night-time atmospheric oxidant NO3˙ damage aromatic amino acids?

Duanne C. E. Sigmund; Uta Wille

doi:10.1039/B803456G

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Chemical Communications

Issue 18, 2008

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Can the night-time atmospheric oxidant NO₃˙ damage aromatic amino acids?

Duanne C. E. Sigmund and Uta Wille

Chem. Commun., 2008, 2121-2123

DOI: 10.1039/B803456G
Received 28 Feb 2008, Accepted 17 Mar 2008
First published on the web 02 Apr 2008

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Reaction of nitrate radicals, NO₃˙, with aromatic amino acids leads to irreversible oxidative functionalization at the β-position or at the aromatic ring, suggesting that this important atmospheric oxidant could potentially cause damage to peptides lining the respiratory tract and may contribute to pollution-derived diseases.

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¹H NMR spectra for 1b, 5a, 7b and 14b; experimental procedures, LC/HR-MS(ESI) spectra for all products of the reaction of NO ₃ radical with 1, 2 and 4
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Chemical Communications

Can the night-time atmospheric oxidant NO₃˙ damage aromatic amino acids?

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