Large mixed metal nitride clusters encapsulated in a small cage: the confinement of the C68-based clusterfullerenes

Shangfeng Yang; Alexey A. Popov; Lothar Dunsch

doi:10.1039/B803200A

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Chemical Communications

Issue 25, 2008

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Large mixed metal nitride clusters encapsulated in a small cage: the confinement of the C₆₈-based clusterfullerenes

Shangfeng Yang , Alexey A. Popov and Lothar Dunsch

Chem. Commun., 2008, 2885-2887

DOI: 10.1039/B803200A
Received 25 Feb 2008, Accepted 17 Mar 2008
First published on the web 18 Apr 2008

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Abstract
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Three novel C₆₈-based mixed metal nitride clusterfullerenes, which comprise of a small non-IPR C₆₈ cage encapsulating large nitride clusters including DySc₂N, LuSc₂N, and Lu₂ScN, have been synthesized and isolated, resulting in overpassing the confinement of the C₆₈ cage.

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Synthesis of M–Sc mixed metal NCFs and detailed isolations of 1–3, comparison of the colors of 1–3 and Sc3N@C68 solutions (in toluene)
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Chemical Communications

Large mixed metal nitride clusters encapsulated in a small cage: the confinement of the C₆₈-based clusterfullerenes

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