Copper-free click chemistry for the in situ crosslinking of photodegradable star polymers

Jeremiah A. Johnson; Jeremy M. Baskin; Carolyn R. Bertozzi; Jeffrey T. Koberstein; Nicholas J. Turro

doi:10.1039/B803043J

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Chemical Communications

Issue 26, 2008

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Copper-free click chemistry for the in situ crosslinking of photodegradable star polymers

Jeremiah A. Johnson , Jeremy M. Baskin , Carolyn R. Bertozzi , Jeffrey T. Koberstein and Nicholas J. Turro

Chem. Commun., 2008, 3064-3066

DOI: 10.1039/B803043J
Received 21 Feb 2008, Accepted 25 Mar 2008
First published on the web 24 Apr 2008

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Bifunctional, fluorinated cyclooctynes were used for the in situ “click” crosslinking of azide-terminated photodegradable star polymers, yielding photodegradable polymeric model networks with well-defined structures and tunable gelation times.

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Jeremiah A. Johnson
Jeremy M. Baskin
Carolyn R. Bertozzi
Jeffrey T. Koberstein
Nicholas J. Turro

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Chemical Communications

Copper-free click chemistry for the in situ crosslinking of photodegradable star polymers

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