Issue 24, 2008
From the journal:

Chemical Communications

Phosphoesterase activity of polyoxomolybdates: diffusion ordered NMR spectroscopy as a tool for obtaining insights into the reactivity of polyoxometalate clusters†

Luk Van Lokeren,a   Els Cartuyvels,b   Gregory Absillis,b   Rudolph Willema  and  Tatjana N. Parac-Vogt*b  

* Corresponding authors

a Vrije Universiteit Brussels, High Resolution NMR centrum, Pleinlaan 2, Brussels, Belgium

b Katholieke Universiteit Leuven, Department of Chemistry, Celestijnenlaan 200F, Leuven, Belgium
E-mail: Tatjana.Vogt@chem.kuleuven.be

Abstract

Diffusion ordered NMR spectroscopy (DOSY NMR) is shown to be an excellent tool for observing reactive transients in the hydrolysis of the phosphatase model substrate (p-nitrophenyl)phosphate (NPP) promoted by polyoxomolybdate.

Graphical abstract: Phosphoesterase activity of polyoxomolybdates: diffusion ordered NMR spectroscopy as a tool for obtaining insights into the reactivity of polyoxometalate clusters

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B802671H
Article type
Communication
Submitted
15 Feb 2008
Accepted
05 Mar 2008
First published
04 Apr 2008

Chem. Commun., 2008, 2774-2776

Permissions

Request permissions

Phosphoesterase activity of polyoxomolybdates: diffusion ordered NMR spectroscopy as a tool for obtaining insights into the reactivity of polyoxometalate clusters

L. V. Lokeren, E. Cartuyvels, G. Absillis, R. Willem and T. N. Parac-Vogt, Chem. Commun., 2008, 2774 DOI: 10.1039/B802671H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements